Sorption and Desorption Studies on Toxic Metals From Brewery Effluent Using Eggshell as Adsorbent

Ayodele Rotimi ipeaiyeda, Godswill Okeoghene Tesi

Abstract


The adsorption capacity of eggshell in removing Pb2+, Ni2+, Mn2+, Zn2+ and Co2+ from standard solution and consolidated brewery effluent was investigated in this study. The sorption process dependent on pH, contact time, initial metal ion concentration and sorbent dosage with pH 7.0 being the optimum value, and maximum sorption was attained within the first 60 minutes. The equilibrium sorption data followed the Langmuir and Freundlich isotherms with R2 ranges of 0.834 – 0.993 and 0.939 – 0.998 respectively. The kinetic data were best described with pseudo second order kinetic. Desorption of sorbed metal ions was efficient with 3.0 mol/L NaOH. The affinity of metal ion sorption was in the order of Co2+ > Pb2+ > Ni2+ > Zn2+ > Mn2+. The percentage adsorptions of Mn2+ and Zn2+ from the brewery effluent were 95.86% and 44.29% respectively, while the corresponding percentage desorption of Mn2+ and Zn2+ were 19.94% and 35.48% respectively.

Keywords


Eggshell; Brewery effluent; Sorption; Desorption; Toxic metals.

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References


Acar, F. N., & Malkov, E. (2004). The removal of chromium(VI) from aqueous solutions by Fagus orientalis L. Bioresource Technology , 94(1), 13 – 15.

Ahalya, N., Ramachandra, T. V., & Kanamadi, R. D. (2003). Biosorption of heavy metals. Research Journal of Chemistry and Environment, 7, 71 – 78.

AjayKumar, A. V., Darwish, N. A., & Hilal, N. (2009). Study of various parameters in the biosorption of heavy metals on activated sludge. World Applied Sciences Journal, 5, 2 – 40.

Aksu, S., & Akpinar, D. (2000). Modelling of simultaneous biosorption of phenol and nickel (II) onto dried aerobic activated sludge. Separation and purification Technology, 21(1–2), 87 – 99.

Aksu, Z., & Isoglu, I. A. (2005). Removal of copper(II) ions from aqueous solution by biosorption onto agricultural waste sugar beet pulp. Process Biochemistry, 40(9), 3031 – 3044.

Al-Qodah, Z. (2006). Biosorption of heavy metal ions from aqueous solutions by activated sludge. Desalination, 196(1-3), 164 – 176.

Basha, C. A., Selvi, S. J., Ramasamy, E., & Chellammal, S. (2008). Removal of arsenic and sulphate from the copper smelting industrial effluent. Chemical Engineering Journal, 141, 89 – 98.

Chojnacka, K. (2005). Biosorption of Cr(III) ions by eggshells. Journal of Hazardous Materials B121, 167 – 173.

Das, N., Karthika, P., Vimala, R., & Vinodhini, V. (2008). Use of natural products as biosorbent of heavy metals—An overview. Natural Product Radiance, 7(2), 133 – 138.

Gazcó, L. G., (2001). The key microbial processes in the removal of toxic metals and radionuclides from the environmental. Central European Journal of Occupational Environmental Medicine, 7(3), 178 – 185.

Gong, R., Ding, Y., Liu, H., Chen, Q., & Liu, Z. (2005). Lead biosorption and desorption by intact and pretreated Spirulina maxima biomass. Chemosphere, 58(1), 125–130.

He, J., Ma, W., He, J., Zhao, J., & Yu, J. C. (2002). Photooxidation of azo dye in aqueous dispersions of H2O2/FeOOH. Applied Catalysis B: Environmental, 39(2), 211-220

Hernández–Montoya, V., Mendoza–Castillo, D. I., Bonilla–Petriciolet, A., Montes–Morán, M. A., & Perez–Cruz, M. A. (2011). Role of the pericarp of Carya Illinoinensis as biosorbent and as precursor of activated carbon for the removal of lead and acid blue 25 in aqueous solutions. Journal of Analytical and Applied Pyrolysis, 92(1), 143 – 151.

Horsfall, M., & Spiff, A. I. (2004). Studies on the effect of pH on the sorption of Pb2+ and Cd2+ ions from aqueous solutions by Caladium bicolor (wild cocoyam) biomass. Electronic Journal of Biotechnology, 7(3), 313-323.

Horsfall, M., & Spiff, I. A. (2005). Effects of temperature on the sorption of Pb2+ and Cd2+ from aqueous solution by Caladium bicolor (Wild cocoyam) biomass. Electronic Journal of Biotechnology, 8(2). 1010-1013.

Ho, Y. S. (2003). Removal of copper from aqueous solution by tree fern. Water Research, 37(10), 2323 – 2330.

Ishikawa, S., & Suyama, K. (1998). Recovery and refining of Au by goldcyanide ion biosorption using animal fibrous proteins. Applied Biochemistry Biotehnology, 70(72), 719 – 728.

Ishikawa, S. I., Suyama, K., Arihara, K., & Itoh, M. (2002). Upkate and recovery of gold ions from electroplating waste using eggshell membrane. Bioresource Technology, 81(3), 210 – 206.

Krishnan, K. A., & Anirudhan, T. S. (2003). Removal of cadmium (II) from aqueous solutions by steam-activated sulphurised carbon prepared from sugar cane bagasse pith: Kinetics and equilibrium studies. Water SA, 29(2), 147 – 156.

Lim, J., Kang, H., Kim, L., & Ko, S. (2008). Removal of heavy metals by sawdust adsorption: Equilibrium and kinetic studies. Environmental Engineering Research, 13(2), 79 – 84.

Liu, W., Zhang, J., Zhang, C. Wang, Y., & Li, Y. (2010). Adsorptive removal of Cr(VI) by Fe—Modified activated carbon prepared from Trapa natans husk. Chemical Engineering Journal, 162(2), 677 – 684.

Mahmood, T., Malik, S. A., & Hussain, S. T. (2010). Biosorption and recovery of heavy metals from aqueous solutions by Eichhornia crassipes (water hyacinth) ash. Bioresource, 5(2), 1244 – 1256.

Makata, L. M., Sajidu, S. M. I., Masamba, W. R. L., & Mwatseteza, J. F. (2010). Cadmium sorption by Moringa stenopetala and Moringa oleifera seed powders. Batch, time, temperature, pH and adsorption isotherm studies. International Journal of Water Resources and Environmental Engineering, 2(3), 50 – 59.

Nakajima, A., & Sakaguchi, T. (1993). Uptake and recovery of gold by immobilized persimmon tannin. Journal of Chemical Technology Biotechnology 57(4), 321 – 326.

Oboh, I., Aluyor, E., & Audu, T. (2009). Biosorption of heavy metal ions from aqueous solutions using a biomaterial. Leonardo Journal of Sciences, 14, 58–65.

Oliveira, E. A., Montanher, S. F., Andrade, A. D., Nobrega, J. A., & Rollemberg, M. C. (2005). Equilibrium studies for the sorption of chromium and nickel from aqueous solutions using raw rice bran. Process Biochemistry, 40(11), 3485 – 3490.

Rashed, M. N. (2006). Fruits stones as adsorbents for the removal of lead ion from polluted water. Environmental Monitoring and Assessment, 119(1-3), 31-41.

Rao, H. J., Kalyani, G., Rao, K. V., Kumar, T. A., Mariadas, K., Kumar, Y. P., Vijetha, P., Pallavi, P., Sumalatha, B., & Kumaraswamy, K. (2010). Kinetic studies on biosorption of lead from aqueous solutions using eggshell powder. International Journal of Biotechnology and Biochemistry, 6(6), 957 – 968.

Sajidu, S. M. I., Henry, E. M. T., Persson, I., Masamba, W. R. L., & Kayambazinthu, D. (2006). pH dependence of sorption of Cd2+, Zn2+, Cu2+ and Cr3+, on crude water and sodium chloride extracts of Moringa stenopetala and Moringa oleifera. African Journal of Biotechnoogy, 5(23), 2397 – 2401.

Sharma, P., Kumari, P., Srivastava, M. M., & Srivastava, S. (2007). Ternany oleifera seeds. Bioresource. Technology, 98(2), 474 – 477.

Singha, B., & Das, S. K. 2011. Biosorption of Cr(VI) ions from aqueous solutions: Kinetics, equilibrium, thermodynamics and desorption studies. Colloids and surfaces B: Biointerfaces, 84(1), 221-232.

Tseng, R. L., & Tseng, S. K. (2005). Pore structure and adsorption performance of the KOH—Activated carbon prepared from corncob. Journal of Colloid and Interface Science, 287(2), 428 – 437.

Vecchio, A., Finoli, C., Di Simine, D., & Andreoni, V. (1998). Heavy metal biosorption by bacterial cells. Fresenius Journal of Analytical Chemistry 361(4), 338 – 342.

Venkata, M. S., Ramanaiah, S. V., Rajkumar, B., & Sarma, P. N. (2007). Removal of fluoride from aqueous phase by biosorption onto algal biosorbent Spirogura sp.–IO2: sorption mechanism elucidation. Journal of Hazardous Materials, 141(3), 465 – 474.

Venkata, M. S., Rao, N. C., & Karthikeyan, J. (2002). Adsorption removal of direct azo dye aqueous phase onto coal based sorbents—A kinetic and mechanistic study. Journal Hazardous Material, 90(2), 189 – 204.

Vieira, R. H. S. F., & Volesky, B. (2000). Biosorption: A solution to pollution. International Microbiology, 3, 17 – 24

Vijayaraghavan, K., Palanivelu, K., & Velan, M. (2006). Biosorption of copper (II) and cobalt (II) from aqueous solutions by crab shell particles. Bioresource Technology, 97(12), 1411 – 1419.

Wang, W., Chen, B., Huang, Y. & Cao, J. (2010). Evaluation of eggshell membrane-based bio-adsorbent for solid–phase extraction of linear alkylbenzene sulfonates coupled with performance liquid chromatography. Journal of Chromatography A, 1217(36), 5659 – 5664.

Yasemin, B., & Tez, Z. (2007). Adsorption studies on ground shells of hazelnut and almond. Journal of Hazardous Materials, 149(1), 35 – 41.

Zheng, J., Feng, H., Lam, M. H., Lam, P. K., Ding, Y., & Yu, H. (2009). Removal of Cu (II) in aqueous media by biosorption using water hyacinth roots as a biosorbent material. Journal of Hazardous Materials, 171(1-3), 780 – 785.




DOI: http://dx.doi.org/10.3968/5394

DOI (PDF): http://dx.doi.org/10.3968/g6138

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